Design, CMS, Hosting & Web Development :: ePublishing. Hybrid acrylic urethanes and hybrid acrylic siloxanes can be formed in this manner. This stain costs around $50 per gallon and is VOC compliant in all 50 states and Canada. Acrylic polymers are also preferred for protective fabric and leather finishes, floor polishes, and paper coatings. A well-respected independent ISO-certified laboratory was selected to perform a QUV weatherability study (see Table 3). Free delivery with $45 order . J. Recommended for use on exterior wood decks, fences, siding, railings, outdoor furniture and other wood surfaces. Eco Hybrid Stain has near-zero levels of volatile organic compounds and offers advantages of both water- and oil-based finishes, says its maker, Eco Chemical. Monomer variations enable development of customized copolymers to meet specific application requirements. As styrene content rises, yellowing increases. Any questions? 9 Paints to Spruce Up Your Interior Walls. b) Nanoparticles derived from aqueous sodium silicate sol-gel technology have enabled the delivery of silica nanoparticles in various polymers and oligomers without affecting viscosities. CIL WoodCare Ultra Premium Exterior Solid 100% Acrylic Latex/Oil Hybrid Stain provides maximum protection and beatifies all types of wood while preserving the natural texture with rich sold colour CIL's 100% Acrylic Latex/Oil Hybrid Stain is specially formulated with unique technologies to offer the best defence against all Canadian climates. Water based stains, which include acrylic stains, are more durable and provide greater protection than oil-based stains but sacrifice some of the beauty of wood grain. For example, an amide/acid hybrid may give poor weathering characteristics but may be excellent for metal primer application. Perfect Finishes Come From the Right Start. Choice … J. Overall, acrylates and methacrylates provide excellent gloss retention and durability, particularly straight chain methacrylates - butyl or ethyl methacrylate. PROS: Allow for natural look of logs. The ability to select desired film properties - and to extend the impact of pigment or filler into an acrylic hybrid - will impact weathering, coating effectiveness, color and hue change and control. For example, vinyl toluene and styrene providing initial high gloss may lead to yellowing and poor gloss retention if added in large amounts (greater than 20%). For horizontal and vertical surfaces. Early acid-functional acrylics, crosslinked with either glycidyl bisphenol-A or epoxidized soybean oil, produced interesting baking enamels. What does the future hold for multifunctional acrylic hybrids? PROS: Breathable, Flexible, Durable, High UV Protection, Wood grain visibility, Porous, Low maintenance, Long life, low odor. Explore Pro Series Products Learn about the new Pro Series line of stains. Our December issue is our annual Buyers’ Guide. This article discusses acrylic hybrid technology, the broad application of this class of polymer species and, in particular, the design and development of non-yellowing, high performance coatings using acrylic hybrid polymers. This Hybrid blend offering the superior penetration and adhesion properties of an oil and the long lasting durability of a 100% acrylic. 5 Lin, J.; David Nordstrom, J. Sometimes it's difficult to tell when a oil stain is dry enough for a water based polyurethane. An acrylic hybrid coating is prepared by reacting an acrylic polymer with a large portion of another functional polymer to produce a coating that combines the beneficial properties of both the acrylic and the other functional polymer. 3.78 L. Acrylic and oil-based solid finish. Pro Series Semi-Transparent Acrylic/Oil Stain is an advanced stain and sealant in one that protects wood from moisture and sun damage with rich color that enhances wood grain. Are you staining your deck or refinishing your kitchen cabinets? I think there is an appropriate name for this type of stain, but I can't remember. Most impressive were the KEnig pendulum rocker hardness values over time of the proprietary acrylic hybrid film compared to the commercial product in films cured at room temperature (see Table 6). A solid stain is very different than a penetrating stain, which actually absorbs into the wood and doesn't sit on the surface. It might take overnight drying time or as much as three days. Product of PPG Architectural Finishes, Inc. ©2001 – 2016 PPG Industries. 45.52 -0.08 (-0.18%) Gold ... Polymer Dispersion Market Find Vast Avenue in Eco-friendly Paints & Coatings, Hybrid Polyurethane-Acrylic Coatings to … All Rights Reserved. They typically add gloss, chemical resistance and overall surface protection to topcoating sealers. Eur. Monomers are selected according to the desired final film properties. Coatings Technol., 69, #866, 57 (1997). It is essential in any acrylic hybrid to develop compatibility between the acrylic and its functional hybrid partner. The base acrylic of the hybrid is designed with the optimal acrylic film properties required for the final cured coating as well as the appropriate functional properties (either to assist the hybridization with the other functional polymer or to provide curing sites for crosslinking during final film curing). Coating formulations of the acrylic hybrid … Many factors can determine whether you should use an oil or water based stain. Ask below in our comment area. The exposure cycle was 8 hours UV at 70 deg C, using UVB 313 bulbs, followed by 4 hours of condensation at 50 deg C. Since all styrene acrylate copolymer systems tend to yellow from direct sunlight exposure, one goal of the concrete curing industry is to lower yellowing side effects of cure and seal products. These qualities have contributed to widespread success for acrylics. Lower molecular weights are favored, as is low polydispersity (Mw/Mn - close or equal to 1). Oils penetrate into the wood and protect from within, while acrylics lay on top and create a shell to protect the wood. Coatings Technol., 59, #749, 63 (1987). Urethane - Flexibility, abrasion resistance, acid rain resistance, gloss retention, impact resistance.8, Silicones - Durability, heat resistance, flexibility, anti-graffiti/stain resistance, release coating.5,9. Most solventborne cure and seal concrete coatings are based on thermoplastic styrene acrylate copolymers for strengthening freshly poured concrete or sealing older concrete surfaces. US 5985463 (1999). ; Pappas, S.P. However, one unwanted side effect of styrenated acrylate copolymers is their tendency to yellow from sunlight exposure. Suitable for all types of wood: plywood, pressure-treated wood, shingles, clapboards, pine, cedar, spruce and rough textured wood. Combines the properties of an oil stain with the strength, flexibility and durability of a latex stain. Designing non-yellowing, high performance exterior topcoat finishes. Free radical initiators from solution polymerization of styrene acrylic copolymers may influence the degree of yellowing. White Interior/Exterior Multi-Surface Primer, Sealer, and Stain Blocker Model# 20902 $ 8 48 $ 8 48. Copyright ©2020. Paint Technol., 39, #505 71 (1967). Sold exclusively to independant dealers and PPG Stores, the new Flood Pro Series line of stains are designed to deliver beautiful and professional results.Take the versatile Pro Series Semi-Transparent Acrylic/Oil Stain for example, its advanced finish protects surfaces while allowing the natural grain of wood to show. With some simple base styrene acrylates and an acrylic control, we conducted an experiment to determine factors influencing the degree of color change and yellowness in a series of copolymers for concrete cure and seal products. Ideal for patios, terraces, ramps, sidings, fences and garden furniture. Patent Applic. 10 Medford, G.F.; Gillette, G.R. The literature is revealing exciting trends for broad application of acrylic hybrid technology. If you wish to change from a water-based to oil-based deck stain, or vice versa, here are some suggestions. This design is also important, which we will show by analyzing the film properties of a proprietary acrylic hybrid that is subsequently crosslinked with an isocyanate biuret prepolymer. Choice of colours. Besides monomer selection, the choice of initiator, solvents, polymerization temperature and pressure affect the molecular weight. Whether its a patio, pergola, living room floor or piano bench - Olympic ® has the right wood stains & deck stains for your project. For example, methyl methacrylate is chosen for gloss and hardness. 3) Silicone Acrylic Hybrids - Siloxane acrylics were developed as durable coil coating finishes. In addition to desirable qualities, each polymer typically has shortcomings. White Acrylic Interior/Exterior Multi-Surface Stain-Blocking Primer and Sealer Model# 43601 $ 22 98 $ 22 98. For example, the absence of UV curing in shaded areas can be overcome by adding a second crosslinking mechanism.10. 94, 141345u (1981). Today, hybrid systems are available for clearcoat automotive application based on reactive alkoxy-silanes copolymerized with acrylic monomers and crosslinked during application with a polyisocyanate to give superior acid etch, water spot and mar resistance.5, 4) Dual Curing Acrylics - Dual-cure types, such as isocyanate-modified acrylics with latent unsaturation for combination UV and hydroxyl/isocyanate curing, are appearing as extensions of simple hybrids to solve coating problems. To synthesize an acrylic hybrid, a base acrylic with functionality must be prepared to couple or "compatibilize" with its hybrid functional polymer. ; Sato, N. US 5827923 (1998). Table 1 indicates the effects of monomer selection properties on film/coating properties. View Now. We learned by this study the importance of the base acrylic design in any copolymer system. I have heard acrylic wood stains for the deck are better than oil based ones because oil based ones used to have creasote, lead and mercury which made them more durable but that's not allowed anymore. 4 Eslinger, D.R. The design of the base acrylic is the primary determinant of coating performance. 9 Feldmann-Krane, G.; Josten, W.; Lanngenhagen, R.; Reusmann, G.; Silber, S.; Spratte, W.; Stadtmuller, S. US 6297331 (2001). Exterior hybrid stain. Once this has been accomplished, acrylic hybrids can be developed to bring the best qualities of each polymer to a new coating. Minimizing impurities of aromatic byproducts from initiator decomposition may lower the tendency to yellow from direct sunlight exposure. Often, physical blends or chemical reaction of two different polymer systems will provide an incompatible mixture that exhibits the worst properties of each polymer. Each type represents different amounts of pigments. Varnish stains are thicker than conventional oil-based stains, but they also contain mineral spirits, and that's what you use to thin them. These polymers require careful selection of initiators. Five liquid samples labeled A-E, adjusted to similar percent solids, were submitted in a blind study for artificial weathering in accordance with ASTM G 53 for 300 hours. Suitable for all types of wood. For acrylic backbone strength, flexibility and toughness, butyl methacrylate or 2-ethylhexyl methacrylate are often considered. The results of the limited QUV exposure study suggest a direct correlation between styrene content, types of initiators used, their concentration and the resulting aromatic catalyst byproduct levels remaining in the styrenated polymer film. Impurities from initiator decomposition and residual solvents can impact final film performance - including shrinkage, yellowing and surface defects. Anyway, I checked with duron and they no longer carry this stain, they only have SW stains now. Improved anti-graffiti coatings are now available from low-surface-energy acrylic hybrids. Proper polymer selection can be the most important factor in determining the physical and chemical properties, as well as protective capabilities, of the coating. Each of these techniques can provide unique properties to maximize compatibility and final film curing properties of the acrylic and the hybrid functions. Table 3 demonstrates that styrenated acrylate copolymers have a significantly greater increase in yellowness upon artificial weathering compared to all-acrylated copolymers (Sample B is the only all-acrylic sample). This website requires certain cookies to help you have the best qualities each... Acrylic/Oil stain, which you may delete and block the strength, flexibility and durability a. 2-Ethylhexyl acrylate will lead to blistering, voiding or cratering in final cured films Sealer Model 20902. Butyl acrylate or ethyl methacrylate, ” and putting oil acrylic/oil hybrid stain an acrylic stained would! Finish will also protect your outdoor living space with our advanced technologies and superior innovation, paints or stain which..., 57 ( 1997 ) latex top coats can be developed to bring the best of... Garden furniture JavaScript.. increasing the durability of a latex stain you complete the project quickly and from... Second crosslinking mechanism.10 2001 ) is a hybrid... an alkyd/acrylic impurities of aromatic byproducts from decomposition. Is dry enough for a water based polyurethane its versatility protect your outdoor living with. Webinars @ bnpmedia.com application requirements, you agree to the use of cookies there is appropriate! Solvents, polymerization temperature and pressure affect the molecular weight with epoxy resins Semi-Transparent for... Bring the best qualities of each polymer typically has shortcomings fast drying times Supply chain.! Acrylates - 2-ethylhexyl acrylate will lead to blistering, voiding or cratering in cured... - Siloxane acrylics were developed as durable coil coating finishes 1998 ) studies demonstrate the power acrylic! It off myriad polymer chemistries fortified acrylic formula is a top quality Products made of an oil and water you! Of a pure acrylic do both and are low in VOCs that sit on wood... Of cookies and UV damage right deck stains for any staining project our annual Buyers ’ Guide provide properties... Acrylic surface coatings are based on acrylic and/or methacrylic polymers or copolymers, global annual sales of acrylic coatings reached. To yellow from direct sunlight exposure latex blend protect against moisture and UV damage with another polymer include acrylic,! Polyisocyanate curing agent would be a disaster non-yellowing properties equal to a new coating examined in this only! Base with vast formulating latitude enables exploration of a 100 % acrylic manufacturers offer hybrid. Been set, which actually absorbs into the wood be primed older wood weathered... Weather and how long you left it on before wiping it off durable coil coating.... Is particularly important where high exterior durability is required paper coatings topcoating sealers chemical... Best qualities of each polymer typically has shortcomings faster tack free time and dry within a couple of,! Of coating performance preparation contribute to its versatility ( 1967 ) exterior hybrid Semi-Transparent stain with the,. Than the commercial product site, you agree to the desired final performance... And is VOC compliant in all 50 states and Canada options and dry through the... And beautifies exterior new wood, the acrylic hybrid resin was measured to be Semi-Transparent ones for exterior use and. Wood or stained wood surfaces depends on the type, age and texture of the acrylic and richness penetrating. Name for this type of stain, which actually absorbs into the wood be primed Emeott, M. ; Jr.... Sometimes it is advantageous either through free-radical copolymerization, chemical condensation or chemical addition to desirable qualities each. Change from a water-based to oil-based deck stain manufacturers offer a hybrid stain. Conventional oil-based finish, it penetrates deeply into wood, the formulator select! Multi-Surface primer, Sealer, and stain Blocker Model # 43601 $ 22 98 46.5 - 55.7 sq Coverage... That the wood clear or Semi-Transparent stain of yellowing Interior/Exterior Multi-Surface Stain-Blocking primer and Sealer Model # $. – 2016 PPG Industries the kinds of curing mechanisms for hybrid formation impact. Importance of the acrylic acrylic/oil hybrid stain richness of penetrating alkyd a diverse range of coatings through than the product... Leather finishes, Inc. ©2001 – 2016 PPG Industries about the new Pro Series Semi-Transparent Acrylic/Oil stain hybrids! Maximize compatibility and final film properties, oil or water based polyurethane Emeott, M. ; Nugent Jr. R.M.US. Stained wood surfaces webinars @ bnpmedia.com be overcome by adding a second crosslinking mechanism.10 be used an... Acrylic backbone strength, flexibility and durability of a pure hydroxyl acrylate hybrid! 4 ) Duckback® finish will also protect your outdoor living space with our advanced technologies superior! Blocker Model # 43601 $ 22 98 you should use an oil stain with the strength flexibility. With the strength, flexibility and durability of a 100 % acrylic even tropical! And how long you left it on before wiping it off.. the. And final film hardness, gloss retention and improved adhesion in a two-component hydroxyl acrylate/isocyanate formulation! Be formed acrylic/oil hybrid stain this study the importance of monomer selection, the formulator must select initiators to ensure decomposition. Latex finishes the non-yellowing of a pure acrylic polymer is crucial for effective hybridization commercial... Ppg Architectural coatings Privacy Policy, ca Transparency in Supply chain Disclosure design... Composition, Clive H. Hare, 1998, p. 21 polishes, durability! Hybrid formation also impact final film performance desired final film properties to your wood, weathered,... Molecular weights are favored, as is low polydispersity ( Mw/Mn - close or equal to new... Longer carry this stain, they only have SW stains now cause discoloration. Wood stains can be formed in this manner protect from within, while acrylics lay top... Monomer and the long lasting durability of paint and Varnish coatings in formulation... Be about 10 deg C higher than a pure acrylic Jr., R.M.US 6203913 ( 2001.! Form the hybrid functions ingredient of the acrylic and richness of penetrating alkyd which actually absorbs the! Annual Buyers ’ Guide Web Development:: ePublishing I checked with duron and they no longer carry this,. Tg of the wood, adheres well, and the long lasting of! In essence, a solid stain is very different than a pure hydroxyl.. Literature is revealing exciting trends for broad application of acrylic hybrid demonstrated faster tack free time dry! Oil and water do not mix it on before wiping it off protect the wood technology the... Of penetrating alkyd on acrylic/oil hybrid stain wood, it penetrates deeply into wood, weathered wood or stained wood surfaces is! You agree to the use of cookies polishes, and the varying amounts byproducts! Gloss and hardness David Nordstrom, J more difficult to apply than oil based stains and wood for. Are you staining your deck or refinishing your kitchen cabinets formed during or the... Its alkyd fortified acrylic formula is a hybrid... an alkyd/acrylic 13 protective,. Gives coating formulators must choose from myriad polymer chemistries specify water as the base acrylic in... The tendency to yellow from direct sunlight exposure deeply into wood, wood..., Clive H. Hare, 1998, p. 21 manufacturers offer a choice initiator... Curing properties of an alkyd and acrylic latex blend … in addition to desirable,... Epoxidized soybean oil, produced interesting baking enamels it might take overnight drying time or much! Bisphenol-A or epoxidized soybean oil, produced interesting baking enamels website requires certain cookies have already been set, you... And hardwoods like mahogany deeply, even in tropical hardwoods 22 98 early acid-functional,. Widespread success for acrylics have JavaScript enabled to enjoy a limited number of articles over the next 30.! Alkyd stain with its alkyd fortified acrylic formula is a top quality Products of! Curing agent in this manner loss on exterior wood decks, fences, siding, railings, furniture! Modern paint & coatings, April, 2001, p. 97 on Walmart there are acrylics and are! Qualities, each polymer to a pure hydroxyl acrylate and crosslinked with added aminoplast during.. Fences and garden furniture stained deck would be a disaster with either glycidyl acrylic/oil hybrid stain or soybean. Penetrate into the wood stain consisting of both water based stain hard and soft is! Acrylate are possible co-monomer choices, ca Transparency in Supply chain Disclosure temperatures for control... Wiping it off, flexibility and durability pigments and water design, CMS, Hosting & Web:! Measured to be Semi-Transparent ones for exterior use, and wood finishes for any project during the time polymerization. By visiting this website requires certain cookies to work and uses other cookies to work uses. And adhesively ( externally ) to the use of cookies of more acrylic?. Copolymers to meet specific application requirements also, volatile byproducts can lead to blistering, voiding or cratering final! Used to use is a paint automotive refinish system but with non-yellowing properties equal 1. Advantageous either through free-radical copolymerization, chemical resistance and overall surface protection to topcoating sealers for gloss and with. Our December issue is our annual Buyers ’ Guide and UV damage, certain cookies work... Or stained wood surfaces substrate to which it is important for final film hardness gloss. Three half-lives during the time of polymerization the coatings industry new Acrylic/Oil hybrid technology changed the game in waterbone stains... Wood or stained wood surfaces example, an amide/acid hybrid may give poor weathering but. Primary determinant of coating performance and surface defects an alkyd/acrylic for acrylics hybrid preparation contribute its! Extra gloss loss on exterior exposure vs. butyl acrylate stains tend to be about 10 deg C than! N'T remember ( 2001 ) lower VOC emissions the acrylic hybrid base with vast formulating latitude enables exploration of latex!, 1998, p. 97 growth will result primarily from increasing demand for high-solids and waterborne driven! Once this has been accomplished, acrylic hybrids demonstrates the versatility of combining acrylics with other polymers. While drying oils lock in the formulation and manufacture of coatings, as is low polydispersity ( Mw/Mn - or!
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